D. V. Goia and E. Matijevic, New J. Chem, p.1203, 1998.

H. Bönnemann and R. M. Richards, Eur. J. Inorg. Chem, p.2455, 2001.

M. A. Watzky and R. G. Finke, Chem. Mater, vol.9, p.3083, 1997.

K. Torigoe, K. Esumi, and . Langmuir, , vol.9, p.1664, 1993.

P. Braunstein and J. Rosé, Metal Clusters in Chemistry

P. Braunstein and L. A. Oro, , vol.2, p.616, 1999.

M. T. Reetz, W. Helbig, and S. A. Quaiser, Chem. Mater, 1995.

J. M. Thomas, B. F. Johnson, R. Raja, G. Sankar, and P. Midgley, Acc. Chem. Res, vol.36, p.20, 2003.

G. Mattei, C. Maurizio, P. Mazzoldi, F. D'acapito, G. Battaglin et al., Phys. Rev. B, p.71, 2005.

J. Belloni, M. Mostafavi, H. Remita, J. L. Marignier, and M. O. Delcourt, New J. Chem, p.1239, 1998.

G. Brieger and T. J. Nestrick, Chem. Rev, vol.74, pp.567-580, 1974.

G. Zassinovich, G. Mestroni, and S. Gladiali, Chem. Rev, vol.92, pp.1051-1069, 1992.

C. Wang, X. Wu, and . Xiao, J. Chem. Asian. J, vol.3, pp.1750-1770, 2008.

J. Huot, J. F. Pelletier, G. Liang, M. Sutton, and R. Schultz, J. Alloys Compd, vol.330, pp.727-731, 2002.

P. Chen, Z. Xiong, J. Luo, J. Lin, and K. L. Tan, Nature, vol.420, pp.302-304, 2002.

N. L. Rosi, J. Eckert, M. Eddaoudi, D. T. Vodak, J. Kim et al., Science, vol.300, pp.1127-1129, 2003.

L. Schlapbach and A. Zuttel, Nature, vol.414, pp.353-358, 2001.

D. J. Browning, M. L. Gerrard, J. B. Lakeman, I. M. Mellor, R. J. Mortimer et al., Nano Lett, vol.2, pp.201-205, 2002.

A. C. Dillon, K. M. Jones, T. A. Bekkedahl, C. H. Kiang, D. S. Bethune et al., Nature, vol.386, pp.377-379, 1997.

K. J. Gross, G. J. Thomas, and C. M. Jensen, J. Alloys Compd, vol.330, pp.683-690, 2002.

, tris(trimethylphosphine)cobalt was obtained as blue-violet solid 720 mg (95%) and stored in a glove box. This catalyst has already been fully characterized in the literature, vol.201

, General procedure for the synthesis of HCoN 2 (PPh 3 ) 3 : Under an argon atmosphere, Co(acac) 3 (3 g, 8.42 mmol, 1 equiv

, Et 2 O. The mixture is then cooled to -50 °C and triisobutylaluminium was added (33.7 mL, 33.7 mmol, 4 equiv.). The reaction mixture was stirred and the temperature was raised

, Commercial trimethylphosphine solution (1 M THF, 40 mL, 40 mmol, 4 equiv.) was added and the resulting mixture was stirred at room temperature. After 15 minutes, NaBH 4 (0.772 g, 20 mmol, 2 equiv.) was added and the reaction mixture was stirred for 3 h at room temperature. The solvent was removed under vacuum

H. F. Klein and H. H. Karsch, Inorg. Chem, p.473, 1975.

A. Yamamoto, S. Kitazume, L. S. Pu, and S. Ikeda, J. Am. Chem. Soc, vol.93, pp.371-380, 1971.

H. F. Klein, Angew. Chem. Int. Ed, vol.11, pp.903-904, 1970.

, The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz, Colorless liquid

. Hz, 1H), 2.72 (brs, 1H), 1.54 (d, J = 6.5 Hz, 3H) ppm

, The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz, Colorless liquid

, The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz, Colorless liquid

Z. , -phenylethenyl)silane 205 : Colorless liquid. 1 H NMR (400 MHz, CDCl 3 ): ? = 7.38 (d, J = 15.0 Hz, 1H), 7.26 -7.33 (m, 5H), 5.84 (d, J = 15.0 Hz, 1H), 0.06 (s, 9H) ppm. (E)-Trimethyl(2-phenylethenyl)silane 206 : Yellow oil. 1 H NMR (400 MHz, CDCl 3 ): ? = 7

Y. Nishihara, D. Saito, K. Tanemura, S. Noyori, and K. Takagi, Org. Lett, vol.11, pp.3546-3549, 2009.

C. Thiot, C. Mioskowski, and A. Wagner, Eur. J. Org. Chem, pp.3219-3227, 2009.

, CDCl 3 ): ? = 7.37 (dd

4. Hz, , vol.7

, 1,1'-(1,2-ethenediyl)bis(4-butyl)benzene 210 : White solid. 1 H NMR (400 MHz, CDCl, vol.3

T. Bosanac and C. S. Wilcox, Org. Lett, vol.6, pp.2321-2324, 2004.

N. Jeong, Angew. Chem. Int. Ed, vol.45, pp.8134-8138, 2006.

J. Liu and B. Li, Synth. Commun, vol.37, pp.3273-3278, 2007.

Y. Zhang, W. Ye, X. Leng, Y. He, H. Zhang et al., Tetrahedron Lett, vol.57, pp.4203-4206, 2016.

, 1,1'-(1,2-ethenediyl)bis(4-butyl)benzene 211 : White solid. 1 H NMR (400 MHz, CDCl, vol.3

, Hz, 4H), 7.02 (d, J = 8.2 Hz, 4H), vol.2

2. Hz, 75 (s, 3H), 5.51 (dt, vol.3

, Hz, 2H), 7.17 (d, J = 8.7 Hz, 2H) ppm

, CDCl 3 ): ? = 7

. Hz,

D. Tzeliioannis, I. D. Petsalakis, G. Theodorakopoulosa, and . Rebek, J. Chem. Phys. Lett, vol.633, pp.99-104, 2015.

M. K. Fujio and . Kagaku, , vol.4, pp.15-18, 1947.

G. Cahiez, O. Gager, and F. Lecomte, Org. Lett, vol.10, pp.5255-5256, 2008.

H. Zhaoa, Y. Wanga, J. Shaa, S. Shenga, and M. Cai, Tetrahedron, vol.64, pp.7517-7523, 2008.

, Phenylacrylic acid 215 : White solid. 1 H NMR (400 MHz, CDCl 3 ): ? = 12.55 (s, 1H), 7.60 (m, 2H), 7.39 (m, 3H), vol.7

, CDCl 3 ): ? = 12

, CDCl 3 ): ? = 10.36 (bs, 1H), 7.25 (m, 5H)

, Cinnamyl alcohol 7 : Colorless solid. 1 H NMR (400 MHz

, Hz, 2H), 7.26 (dd, J = 8.7 Hz, 5.8 Hz, 1H), vol.7

, CDCl 3 ): ? = 7.80 (d, Colorless solid. 1 H NMR (400 MHz, vol.15

, Hz, 2H), 7.50 -7.60 (m, 2H), vol.7, pp.36-43

Y. Zhao, Q. Liu, J. Li, Z. Liu, B. Zhou et al., , vol.12, pp.1870-1872, 2010.

M. Kalinowska, R. Jwisiocka, and W. Lewandowski, J. Mol. Struct, pp.572-580, 2007.

A. K. Schmidt and C. B. Stark, Org. Lett, vol.13, pp.4164-4167, 2011.

M. Shibuya, T. Sato, M. Tomizawa, and Y. Iwabuchi, Chem. Commun, pp.1739-1741, 2009.

, Benzenepropanol: Colorless solid. The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz

. Hz,

, CDCl 3 ): ? = 7.22 -7.35 (m, 5H), 3.82 (dd, J =, vol.12

, CDCl 3 ): ? = 7.35 -7.4 (m, 2H), 7.2 -7.3 (m, 3H), vol.6

, CDCl 3 ): ? = 7.44 -7.40 (m, 2H), 7.35 -7.38 (m, 2H), vol.6

. Hz,

, 5-dimethyl-hex-3-ene-2,5-diol 221 : colorless oil 1 H NMR (400 MHz, CDCl, vol.3, issue.2

S. Y. Zhang, Y. Q. Tu, C. A. Fan, Y. J. Jiang, L. Shi et al., Chem. Eur. J, vol.14, pp.10201-10205, 2008.

O. Hamed, P. M. Henry, and D. P. Becker, Tetrahedron Lett, pp.3514-3517, 2010.

H. Tan and J. H. Espenson, Inorg. Chem, vol.37, pp.467-472, 1998.

, 5-dimethyl-hex-3-ene-2,5-diol 222 : colorless oil 1 H NMR (400 MHz, CDCl, vol.3, issue.2

, Mesitylene: Colorless liquid. The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz

N. and N. , CDCl 3 ): ? = 7.37 -7.40 (m, 2H), 7.29 -7.34 (m, 2H), 7.24 (m, 1H), 6.57 (d, J = 15.6 Hz, 1H), vol.223

, Naphthalene: Colorless solid. The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz, CDCl 3 ): ? = 7.84 (m, 4H), 7.48 (m, 4H) ppm

, Phenanthrene: White solid. The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz

. Hz, Hz, 2H), 8.72 (d, J = 8.0 Hz, 2H) ppm, vol.1

S. Hironao, M. Shigeki, T. Ohkubo, T. Ikawa, T. Kume et al., Chem. Eur. J, vol.14, pp.5109-5111, 2008.

N. Iranpoor, H. Firouzabadi, N. Nowrouziy, and D. Khalili, Phenylacetic acid: White solid. The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz, Tetrahedron, vol.65, 2009.

A. -methoxyphenylacetic, White solid. The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz

, The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz, CDCl 3 ): ? = 7.10 -7.60 (m, 10H) ppm

, 4-Bis(p-methoxyphenyl) buta-1,3-diyne 224 : White solid. 1 H NMR (400 MHz, CDCl, vol.3

, -methoxyphenyl)benzene 225 : White solid. 1 H NMR (400 MHz, vol.2, p.4

J. H. Li, Y. Liang, and X. D. Zhang, Tetrahedron, vol.61, pp.1903-1907, 2005.

V. Cadierno, S. E. García-garrido, and J. J. Gimeno, Am. Chem. Soc, vol.128, pp.15094-15095, 2006.

, ? CoBr, vol.2, issue.2

, E(SCF) = -859.027657006 Hartree

C. X-=-i-2*coi, PH 3 ) 2 = CoI 2 (NH 3 ) 2 + Co, vol.3, p.4

?. Coi, , vol.3

, E(SCF) = -900.179029181 Hartree

, 150 K) = -900.131110 Hartree; Minimal frequency = 23, pp.3704-3705

. S**,