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, tris(trimethylphosphine)cobalt was obtained as blue-violet solid 720 mg (95%) and stored in a glove box. This catalyst has already been fully characterized in the literature, vol.201
, General procedure for the synthesis of HCoN 2 (PPh 3 ) 3 : Under an argon atmosphere, Co(acac) 3 (3 g, 8.42 mmol, 1 equiv
, Et 2 O. The mixture is then cooled to -50 °C and triisobutylaluminium was added (33.7 mL, 33.7 mmol, 4 equiv.). The reaction mixture was stirred and the temperature was raised
, Commercial trimethylphosphine solution (1 M THF, 40 mL, 40 mmol, 4 equiv.) was added and the resulting mixture was stirred at room temperature. After 15 minutes, NaBH 4 (0.772 g, 20 mmol, 2 equiv.) was added and the reaction mixture was stirred for 3 h at room temperature. The solvent was removed under vacuum
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, The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz, Colorless liquid
1H), 2.72 (brs, 1H), 1.54 (d, J = 6.5 Hz, 3H) ppm ,
, The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz, Colorless liquid
, The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz, Colorless liquid
, -phenylethenyl)silane 205 : Colorless liquid. 1 H NMR (400 MHz, CDCl 3 ): ? = 7.38 (d, J = 15.0 Hz, 1H), 7.26 -7.33 (m, 5H), 5.84 (d, J = 15.0 Hz, 1H), 0.06 (s, 9H) ppm. (E)-Trimethyl(2-phenylethenyl)silane 206 : Yellow oil. 1 H NMR (400 MHz, CDCl 3 ): ? = 7
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, CDCl 3 ): ? = 7.37 (dd
, , vol.7
, 1,1'-(1,2-ethenediyl)bis(4-butyl)benzene 210 : White solid. 1 H NMR (400 MHz, CDCl, vol.3
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, 1,1'-(1,2-ethenediyl)bis(4-butyl)benzene 211 : White solid. 1 H NMR (400 MHz, CDCl, vol.3
, Hz, 4H), 7.02 (d, J = 8.2 Hz, 4H), vol.2
75 (s, 3H), 5.51 (dt, vol.3 ,
, Hz, 2H), 7.17 (d, J = 8.7 Hz, 2H) ppm
, CDCl 3 ): ? = 7
,
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, Phenylacrylic acid 215 : White solid. 1 H NMR (400 MHz, CDCl 3 ): ? = 12.55 (s, 1H), 7.60 (m, 2H), 7.39 (m, 3H), vol.7
, CDCl 3 ): ? = 12
, CDCl 3 ): ? = 10.36 (bs, 1H), 7.25 (m, 5H)
, Cinnamyl alcohol 7 : Colorless solid. 1 H NMR (400 MHz
, Hz, 2H), 7.26 (dd, J = 8.7 Hz, 5.8 Hz, 1H), vol.7
, CDCl 3 ): ? = 7.80 (d, Colorless solid. 1 H NMR (400 MHz, vol.15
, Hz, 2H), 7.50 -7.60 (m, 2H), vol.7, pp.36-43
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, Benzenepropanol: Colorless solid. The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz
,
, CDCl 3 ): ? = 7.22 -7.35 (m, 5H), 3.82 (dd, J =, vol.12
, CDCl 3 ): ? = 7.35 -7.4 (m, 2H), 7.2 -7.3 (m, 3H), vol.6
, CDCl 3 ): ? = 7.44 -7.40 (m, 2H), 7.35 -7.38 (m, 2H), vol.6
,
, 5-dimethyl-hex-3-ene-2,5-diol 221 : colorless oil 1 H NMR (400 MHz, CDCl, vol.3, issue.2
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, 5-dimethyl-hex-3-ene-2,5-diol 222 : colorless oil 1 H NMR (400 MHz, CDCl, vol.3, issue.2
, Mesitylene: Colorless liquid. The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz
, CDCl 3 ): ? = 7.37 -7.40 (m, 2H), 7.29 -7.34 (m, 2H), 7.24 (m, 1H), 6.57 (d, J = 15.6 Hz, 1H), vol.223
, Naphthalene: Colorless solid. The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz, CDCl 3 ): ? = 7.84 (m, 4H), 7.48 (m, 4H) ppm
, Phenanthrene: White solid. The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz
Hz, 2H), 8.72 (d, J = 8.0 Hz, 2H) ppm, vol.1 ,
, Chem. Eur. J, vol.14, pp.5109-5111, 2008.
Phenylacetic acid: White solid. The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz, Tetrahedron, vol.65, 2009. ,
White solid. The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz ,
, The proton NMR matches with the commercially available compound. 1 H NMR (400 MHz, CDCl 3 ): ? = 7.10 -7.60 (m, 10H) ppm
, 4-Bis(p-methoxyphenyl) buta-1,3-diyne 224 : White solid. 1 H NMR (400 MHz, CDCl, vol.3
, -methoxyphenyl)benzene 225 : White solid. 1 H NMR (400 MHz, vol.2, p.4
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, Am. Chem. Soc, vol.128, pp.15094-15095, 2006.
, ? CoBr, vol.2, issue.2
, E(SCF) = -859.027657006 Hartree
PH 3 ) 2 = CoI 2 (NH 3 ) 2 + Co, vol.3, p.4 ,
, , vol.3
, E(SCF) = -900.179029181 Hartree
, 150 K) = -900.131110 Hartree; Minimal frequency = 23, pp.3704-3705
,