Rovibrational spin-averaged transitions in the hydrogen molecular ions

Vladimir I Korobov (1) , J.-Ph. Karr (2, 3)

1 BLTP - Bogoliubov Laboratory of Theoretical Physics [Dubna]
2 LKB (Jussieu) - Laboratoire Kastler Brossel
3 UEVE - Université d'Évry-Val-d'Essonne

We reconsider the calculation of rovibrational transition frequencies in hydrogen molecular ions. Some previously neglected contributions, such as the deuteron polarizability, are included into consideration in comparison with our previous work. In particular, one-loop and two-loop QED corrections at mα 7 and mα 8 orders are recalculated in the framework of the adiabatic approximation, with systematic inclusion of corrections associated with vibrational motion. Improved theoretical transitions frequencies are obtained and found to be in very good agreement with recent highprecision spectroscopy experiments in HD +. New values for the mp/me and m d /mp mass ratios are determined.

Domaines: Autre [cond-mat.other]

Vladimir I Korobov, J.-Ph. Karr. Rovibrational spin-averaged transitions in the hydrogen molecular ions. Physical Review A, 2021, 104 (3), ⟨10.1103/PhysRevA.104.032806⟩. ⟨hal-03341673⟩